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Iron oxide-based catalysts for low-temperature selective catalytic reduction of NOx with NH3

  • Naveed Husnain graduated from Bahauddin Zakariya University (Multan, Pakistan) with a bachelor’s degree in mechanical engineering in 2011 and a Master’s degree in mechanical engineering from the National University of Sciences and Technology (Islamabad, Pakistan) in 2014. He joined the Department of Mechanical Engineering, Bahauddin Zakariya University, as a lecturer in 2015 and then joined Shanghai Jiao Tong University (Shanghai, China) as a doctoral student in 2015. His research focus includes SCR, heterogeneous catalysis, catalysts synthesis, and characterization.

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    Enlu Wang obtained his PhD in mechanical engineering from Shanghai Jiao Tong University in 2011. He joined School of Electric Power Energy Engineering, Shanghai Jiao Tong University, in 1989. He was a visiting scholar at the Institute of Process Engineering and Power Plant Technology, University of Stuttgart (Stuttgart, Germany), from 2000 to 2001. He is currently working as an associate professor at the Institute of Thermal Energy Engineering, Shanghai Jiao Tong University. His research focus includes fuel clean combustion technology, mechanism of gas fuel clean combustion, and flue gas heat transfer and water capture.

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    Kai Li graduated from Nanchang Hangkong University (Jiangxi, China) with a bachelor’s degree in aircraft power engineering in 2013 and a Master’s degree in 2015. In the same year, he joined the Institute of Thermal Energy Engineering, Shanghai Jiao Tong University, as a doctoral student.

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    Muhammad Tuoqeer Anwar earned a Master’s degree in mechanical engineering from the National University of Sciences and Technology in 2012. He joined the Department of Mechanical Engineering COMSATS (Sahiwal, Pakistan) as a lecturer in 2012 and then joined Shanghai Jiao Tong University as a doctoral student in 2014.

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    Aamir Mehmood is serving as a lecturer at the University of Engineering and Technology (Faisalabad, Pakistan). He holds a bachelor’s degree in mechanical engineering from the University of Engineering and Technology Taxila and a Master’s degree in energy systems engineering from the National University of Sciences and Technology. He also has work experience as a research associate at the City University of Hong Kong and is still engaged in collaborative research activities with national and international institutes in interested research domains.

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    Mustabshirha Gul graduated from Bahauddin Zakariya University with a bachelor’s degree in mechanical engineering in 2011 and a Master’s degree in mechanical engineering from the University of Engineering and Technology in 2014. She is currently working as a lecturer in the Department of Mechanical Engineering, Bahauddin Zakariya University.

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    Deli Li graduated from Qingdao University of Science and Technology (Qingdao, China) with a bachelor’s degree in thermal energy and power engineering in 2012 and a Master’s degree in thermal engineering from Northeastern University (Shenyang, China) in 2014. Then he joined Shanghai Jiao Tong University as a doctoral student in 2015.

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    Jinda Mao graduated from Nanjing Tech University (Nanjing, China) with a bachelor’s degree in thermal energy and power engineering in 2014. Then he joined the School of Mechanical and Power Engineering, Shanghai Jiao Tong University, as a Master’s student in 2014.

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Published/Copyright: January 23, 2018
Become an author with De Gruyter Brill

Abstract

Selective catalytic reduction (SCR) is now an established NOx removal technology for industrial flue gas as well as for diesel engine exhaust gas. However, it is still a big challenge to develop a novel low-temperature catalyst for NH3-SCR of NOx, especially at a temperature below 200°C. In the past few years, many studies have demonstrated the potential of iron (Fe)-based catalysts as low-temperature catalysts for NH3-SCR of NOx. Herein, we summarize the recent progress and performance of Fe-based catalysts for low-temperature NH3-SCR of NOx. Catalysts are divided into three categories: single FexOy, Fe-based multimetal oxide, and Fe-based multimetal oxide with support catalysts. The catalytic activity and selectivity of Fe-based catalysts are systematically analyzed and summarized in light of some key factors such as activation energy, specific surface area, morphology, crystallinity, preparation method and precursor, acid sites, calcination temperature, other metal dopant/substitute, and redox property of catalysts. In addition, H2O/SO2 tolerance and the NH3-SCR reaction mechanism over Fe-based catalysts, including Eley-Rideal and Langmuir-Hinshelwood mechanism, are emphasized. Lastly, the perspectives and future research directions of low-temperature NH3-SCR of NOx are also proposed.

About the authors

Naveed Husnain

Naveed Husnain graduated from Bahauddin Zakariya University (Multan, Pakistan) with a bachelor’s degree in mechanical engineering in 2011 and a Master’s degree in mechanical engineering from the National University of Sciences and Technology (Islamabad, Pakistan) in 2014. He joined the Department of Mechanical Engineering, Bahauddin Zakariya University, as a lecturer in 2015 and then joined Shanghai Jiao Tong University (Shanghai, China) as a doctoral student in 2015. His research focus includes SCR, heterogeneous catalysis, catalysts synthesis, and characterization.

Enlu Wang

Enlu Wang obtained his PhD in mechanical engineering from Shanghai Jiao Tong University in 2011. He joined School of Electric Power Energy Engineering, Shanghai Jiao Tong University, in 1989. He was a visiting scholar at the Institute of Process Engineering and Power Plant Technology, University of Stuttgart (Stuttgart, Germany), from 2000 to 2001. He is currently working as an associate professor at the Institute of Thermal Energy Engineering, Shanghai Jiao Tong University. His research focus includes fuel clean combustion technology, mechanism of gas fuel clean combustion, and flue gas heat transfer and water capture.

Kai Li

Kai Li graduated from Nanchang Hangkong University (Jiangxi, China) with a bachelor’s degree in aircraft power engineering in 2013 and a Master’s degree in 2015. In the same year, he joined the Institute of Thermal Energy Engineering, Shanghai Jiao Tong University, as a doctoral student.

Muhammad Tuoqeer Anwar

Muhammad Tuoqeer Anwar earned a Master’s degree in mechanical engineering from the National University of Sciences and Technology in 2012. He joined the Department of Mechanical Engineering COMSATS (Sahiwal, Pakistan) as a lecturer in 2012 and then joined Shanghai Jiao Tong University as a doctoral student in 2014.

Aamir Mehmood

Aamir Mehmood is serving as a lecturer at the University of Engineering and Technology (Faisalabad, Pakistan). He holds a bachelor’s degree in mechanical engineering from the University of Engineering and Technology Taxila and a Master’s degree in energy systems engineering from the National University of Sciences and Technology. He also has work experience as a research associate at the City University of Hong Kong and is still engaged in collaborative research activities with national and international institutes in interested research domains.

Mustabshirha Gul

Mustabshirha Gul graduated from Bahauddin Zakariya University with a bachelor’s degree in mechanical engineering in 2011 and a Master’s degree in mechanical engineering from the University of Engineering and Technology in 2014. She is currently working as a lecturer in the Department of Mechanical Engineering, Bahauddin Zakariya University.

Deli Li

Deli Li graduated from Qingdao University of Science and Technology (Qingdao, China) with a bachelor’s degree in thermal energy and power engineering in 2012 and a Master’s degree in thermal engineering from Northeastern University (Shenyang, China) in 2014. Then he joined Shanghai Jiao Tong University as a doctoral student in 2015.

Jinda Mao

Jinda Mao graduated from Nanjing Tech University (Nanjing, China) with a bachelor’s degree in thermal energy and power engineering in 2014. Then he joined the School of Mechanical and Power Engineering, Shanghai Jiao Tong University, as a Master’s student in 2014.

Acknowledgments

This work was supported by the National Natural Science Fund of China (grant no. 50676057).

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Received: 2017-07-26
Accepted: 2017-11-16
Published Online: 2018-01-23
Published in Print: 2019-02-25

©2019 Walter de Gruyter GmbH, Berlin/Boston

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